Difference between revisions of "Transformation of TXA2 to TXB2"
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| Line 24: | Line 24: | ||
|M-1 s-1 | |M-1 s-1 | ||
|NaCl04 (0.1 - 0.2 M) | |NaCl04 (0.1 - 0.2 M) | ||
| + | Temperature: 25°C | ||
| + | |3 | ||
| + | |<ref name="Ross1982”>[http://pubs.acs.org/doi/pdf/10.1021/ja00370a035 A. Ross "Vinyl epoxide hydrolysis reactions" J. Am. Chem. Soc., 1982, 104 (6), pp 1658–1665]</ref> | ||
| + | |- | ||
| + | |8.7e3 | ||
| + | |M-1 s-1 | ||
| + | |KCl (1 M) | ||
Temperature: 25°C | Temperature: 25°C | ||
|3 | |3 | ||
| Line 31: | Line 38: | ||
|M-1 s-1 | |M-1 s-1 | ||
|NaCl04 (0.1 - 0.2 M) | |NaCl04 (0.1 - 0.2 M) | ||
| + | Temperature: 25°C | ||
| + | |4 | ||
| + | |<ref name="Ross1982”>[http://pubs.acs.org/doi/pdf/10.1021/ja00370a035 A. Ross "Vinyl epoxide hydrolysis reactions" J. Am. Chem. Soc., 1982, 104 (6), pp 1658–1665]</ref> | ||
| + | |- | ||
| + | |2.4 e4 | ||
| + | |M-1 s-1 | ||
| + | |KCl (1M) | ||
Temperature: 25°C | Temperature: 25°C | ||
|4 | |4 | ||
| Line 63: | Line 77: | ||
|<ref name="Ross1982”>[http://pubs.acs.org/doi/pdf/10.1021/ja00370a035 A. Ross "Vinyl epoxide hydrolysis reactions" J. Am. Chem. Soc., 1982, 104 (6), pp 1658–1665]</ref> | |<ref name="Ross1982”>[http://pubs.acs.org/doi/pdf/10.1021/ja00370a035 A. Ross "Vinyl epoxide hydrolysis reactions" J. Am. Chem. Soc., 1982, 104 (6), pp 1658–1665]</ref> | ||
|- | |- | ||
| − | + | |35 | |
| + | |M-1 s-1 | ||
| + | |KCl (1M) | ||
| + | Temperature: 25°C | ||
| + | |8 | ||
| + | |<ref name="Ross1982”>[http://pubs.acs.org/doi/pdf/10.1021/ja00370a035 A. Ross "Vinyl epoxide hydrolysis reactions" J. Am. Chem. Soc., 1982, 104 (6), pp 1658–1665]</ref> | ||
| + | |- | ||
|} | |} | ||
== Related Reactions == | == Related Reactions == | ||
* [[Transformation of PGH2 to TXA2 |Transformation of PGH2 to TXA2]] | * [[Transformation of PGH2 to TXA2 |Transformation of PGH2 to TXA2]] | ||
Revision as of 10:49, 2 September 2016
Reaction
Chemical equation
Rate equation
Parameters
| Value | Units | Conditions | Substrate | Reference |
|---|---|---|---|---|
| 3.7e3 ± 0.1e3 | M-1 s-1 | NaCl04 (0.1 - 0.2 M)
Temperature: 25°C |
3 | [1] |
| 8.7e3 | M-1 s-1 | KCl (1 M)
Temperature: 25°C |
3 | [1] |
| 1.1e4 ± 0.1e4 | M-1 s-1 | NaCl04 (0.1 - 0.2 M)
Temperature: 25°C |
4 | [1] |
| 2.4 e4 | M-1 s-1 | KCl (1M)
Temperature: 25°C |
4 | [1] |
| 3.7e3 ± 0.1e3 | M-1 s-1 | NaCl04 (0.1 - 0.2 M)
Temperature: 25°C |
5 | [1] |
| 3.6 ± 0.2 | M-1 s-1 | NaCl04 (0.1 - 0.2 M)
Temperature: 25°C |
6 | [1] |
| 1.7 ± 0.1 | M-1 s-1 | NaCl04 (0.1 - 0.2 M)
Temperature: 25°C |
7 | [1] |
| 26.7 ± 0.9 | M-1 s-1 | NaCl04 (0.1 - 0.2 M)
Temperature: 25°C |
8 | [1] |
| 35 | M-1 s-1 | KCl (1M)
Temperature: 25°C |
8 | [1] |
